Microplastics in packaged water, community stored water, groundwater, and surface water in rivers of Tamil Nadu after the COVID-19 pandemic outbreak.

The increased load of plastic in waste streams after the COVID-19 pandemic outbreak has increased the possibility of microplastics (MPs) contamination channelling through the rivers and infiltrating the aquatic ecosystems. MPs in packaged water, community-stored water, groundwater, and surface water of Kaveri River (KR), Thamirabarani River (TR), Adyar River (AR), and Cooum River (CR) in Tamil Nadu were therefore investigated about 2 years after the COVID-19 pandemic outbreak. Using µFTIR and µRaman spectroscopy, polyamide, polypropylene, polyethylene, ethylene vinyl alcohol copolymer resin, and polyvinyl chloride were identified as the primary polymer types. The average number of MPs was 2.15 ± 1.9 MP/L, 1.1 ± 0.99 MP/L, 5.25 ± 1.15 MP/L, and 4 ± 2.65 MP/L in KR, TR, AR, and CR, respectively, and 1.75 ± 1.26 MP/L in groundwater, and 2.33 ± 1.52 MP/L in community stored water. Only LDPE was detected in recycled plastic-made drinking water bottles. More than 50% of MPs were found to be of size less than 1 mm, with fibrous MPs being the prevalent type, and a notable prevalence of blue-coloured microplastics in all the sample types. The Pollution Load Index (PLI) was >1 in all the rivers. Toxicity rating based on the polymer risk index (PORI) categorized AR and TR at medium risk (category II), compared to KR and CR at considerable risk (category III). Overall pollution risk index (PRI) followed a decreasing trend with CR > AR > KR > TR of considerable to low-risk category. Ecological risk assessment indicates a negligible risk to freshwater biota, except for four sites in the middle and lower stretches of Adyar River (AR - 2, AR - 4) and upper and lower stretches of Cooum River (CR - 1, CR - 3), located adjacent to direct sewer outlets, and one location in the lower stretch of Kaveri River (KR - 9), known for fishing and tourist activities.

Sediment-water exchange and risk assessment of pesticidal persistent organic pollutants in Bharathappuzha and Periyar Riverine region along the Arabian Sea.

Considering the extensive agricultural practices along the perennial rivers, viz. Periyar and Bharathappuzha of Kerala in the southwest coast of India, the first comprehensive surveillance of new and legacy organochlorine pesticides (OCPs) in surface sediment was conducted. Further, the sediment-water exchange fluxes have been elucidated. Mean concentrations of total HCH, DDT and endosulfan were 0.84 ng/g, 0.42 ng/g and 0.30 ng/g for Bharathappuzha Riverine sediment (BRS) and 1.08 ng/g, 0.39 ng/g and 0.35 ng/g for Periyar Riverine sediment (PRS). The dominance α-HCH and ß-HCH isomers in PRS and BRS reflect the ongoing use of technical HCH in Kerala. The calculated KSW in both rivers was very low in comparison with other Indian rivers. The average log K'OC for all the detected OCPs in both the rivers was lower than the predicted log KOC in equilibrium indicating the higher adherence of OCPs to sediment. Furthermore, fugacity fraction (fs/fw) was < 1.0 for all OCPs confirming the net deposition of OCPs into the sediment. Sediment concentrations for each of the OCPs in PRS and BRS did not surpass the threshold effect level and probable effect level as stipulated by the Canadian Council of Ministry of the Environment Guidelines. In addition, all the sites of both rivers had sediment quality guideline quotient (SQGQ) values below 0.1 indicating the absence of significant biological and ecological risks.

Comparison of Cd, Cu, Se, and Zn Concentration in the Muscle and Hepatopancreas of Sepia pharaonis and Uroteuthis duvauceli in the North of Persian Gulf (Iran).

The objective of this research was to examine and contrast the levels of cadmium (Cd), copper (Cu), zinc (Zn), and selenium (Se) in the muscle and hepatopancreas tissues of two species, namely pharaoh cuttlefish (Sepia pharaonis) and Indian squid (Uroteuthis duvauceli), from the Persian Gulf. A total of thirty individuals of each species were gathered in January 2009 from the northern waters of the Persian Gulf. The metal concentrations were significantly higher in muscle tissue (p < 0.05) than in other tissues. S. pharaonis had higher metal concentrations than U. duvauceli. In the muscle and hepatopancreas samples of S. pharaonis, the highest mean concentrations were found to be for Zn (58.45 ± 0.96 µg/g dw) and Cu (1541.47 ± 192.15 µg/g dw), respectively. In U. duvauceli, the highest concentration of measured elements was seen for Zn in both muscle (36.52 ± 0.56 µg/g dw) and hepatopancreas (60.94 ± 2.65 µg/g dw). Se had the lowest concentration among the elements measured in both species. There was a negative and significant correlation between Cu and biometrical factors (total body length and weight) in both muscle and hepatopancreas samples of S. pharaonic and only in the muscle samples of U. duvauceli (p < 0.01, R2 = - 052; p < 0.01, R2 = - 0.055). However, there was a strong correlation between Zn and biometrical factors in hepatopancreas samples of both species. The comparison of metal concentrations with standards revealed that only Cd levels in S. pharaonis exceeded the ESFA and WHO standards, whereas other metals were below the standards.

Polychlorinated biphenyls in bovine milk from a typical informal electronic waste recycling and related source regions in southern India before and after the COVID-19 pandemic outbreak.

For more than a decade, Chennai city in southern India has been evidenced with informal electronic waste (e-waste) recycling and open burning practices as the potential sources for polychlorinated biphenyls (PCBs). PCBs can bioaccumulate in livestock particularly cows grazing on the contaminated soil. The outbreak of the COVID-19 pandemic led to additional challenges associated with waste management practices. Hence this study aims to elucidate twenty-five PCB congeners in bovine milk from the previously reported PCB source regions in Chennai and the suburbs before and after about three years of the pandemic outbreak along electronic waste recycling (EWR), open burning dumps (OBD), and residential (RES) transects. The geomean concentration of Æ©25PCBs in ng/g lipid weight (lw) followed a decreasing trend of EWR (13 ng/g lw) > OBD (8 ng/g lw) > RES (4 ng/g lw). Over 80 % of PCBs stemmed from EWR and OBD transects before and after the pandemic. However, a significant surge in the level of PCB-52 was observed in the OBD transect after the pandemic outbreak. Most toxic PCB congeners, PCB-126 and -169 were significant contributors to TEQs in EWR and OBD transects and can be reasoned with the burning of waste materials and mixed plastics in these transects. The highest average daily dose (ADD) exposure risk was for children from EWR and was significantly higher (p < 0.05) than other transects. Mean ADD-induced TEQ (6.6 pg TEQ/kg-bw/day) from the cows grazing around Kodungaiyur dumpsite slightly exceeded the EU guideline of 5.5 pg TEQ/kg-bw/day after the outbreak of the pandemic due to PCB-126. However, none of the samples exceeded the US FDA (1.5µg/g milk fat) recommendation limits for PCBs in milk fat. Prolonged exposure to such persistent organic pollutants interlinked with the burning of mixed waste in the open dumps can be a public health concern.

An updated status of currently used pesticides in India: Human dietary exposure from an Indian food basket.

Currently used pesticides (CUPs) were introduced to have lower persistence and bioaccumulation, and lesser bioavailability towards non-target species. Nevertheless, CUPs still represent a concern for both human health and the environment. India is an important agricultural country experiencing a conversion from the use of obsolete organochlorine pesticides to a newer generation of phytosanitary products. As for other developing countries, very little is known about the transfer of CUPs to the human diet in India, where systematic monitoring is not in place. In this study, we analyzed ninety four CUPs and detected thirty CUPs in several food products belonging to five types: cereals and pulses, vegetables, fruits, animal-based foods, and water. Samples were taken from markets in Delhi (aggregating food produced all over India) and in the periurban area of Dehradun (northern India) (representing food produced locally and through more traditional practices). Overall, chlorpyrifos and chlorpropham were the most detected CUPs with a detection frequency of 33% and 25%, respectively. Except for vegetables and fruits, the levels of CUPs in all other food types were significantly higher in samples from Delhi (p < 0.05). Exposure dosage of CUPs through different food matrices was calculated, and chlorpropham detected in potatoes had the maximum exposure dosage to humans (2.46 × 10-6 mg/kg/day). Risk analysis based on the hazard quotient technique indicated that chlorpyrifos in rice (2.76 × 10-2) can be a concern.

Air-water exchange and risk assessment of phthalic acid esters during the early phase of COVID-19 pandemic in tropical riverine catchments of India.

Given the increased load of waste plastic in the solid waste stream after the outbreak of the COVID-19 pandemic, we investigated the fate of selected plastic additives along open burning dumps, industrial and residential transects in tropical riverine catchments of India. Polyurethane foam disk passive air samples, surface water and community stored water (CSW) samples were collected along the Adyar River (AR), Cooum River (CR) and canals in Chennai and Daman Ganga River (DG) in Vapi. Among the quantified phthalic acid esters (PAEs), a widely used plastic additive, di(2-ethylhexyl) phthalate (DEHP), was ubiquitous across all the transects. More open drains and leaching of littered single-use plastic items can be the reason for significantly higher (p < 0.05) levels of PAEs in CR over other rivers with a dominance of di-n-butyl phthalate (DnBP). Prevalence of open burning of dumped plastic waste was the possible primary emission source of PAEs in these riverine catchments. Excluding highly soluble dimethyl phthalate (DMP), air-water exchange processes reflected the secondary emission of all the PAEs from the surface water along the open burning sites. Despite the cleansing effect of the oceanic air mass from the Bay of Bengal and the Indian Ocean, the average atmospheric PAE level was two-fold higher in Chennai than Vapi. Even though Vapi is a coastal city along the Arabian Sea, it was impacted by inland air masses during the sampling event. Open burning dumpsites showed a five-fold increase in atmospheric priority PAEs in Chennai city after the outbreak of the COVID-19 pandemic. DnBP was the major contributor to estrogenicity in CSW and DG, and also posed maximum risk for fishes in the open burning transect of these tropical rivers.

Occurrence, Source and Dietary Exposure of Toxic and Essential Elements in the Indian Food Basket.

In this study, representative urban and peri-urban Indian food baskets have been studied for the presence of toxic and essential elements. The concentration of target toxic and essential elements was used to estimate dietary intakes (EDIs) and health risks. Across all food matrices, toxic elements like Cd and Pb were dominant. The highest concentrations of the target elements were found in vegetables, with Cd, Pb, and Ni being beyond permissible limits of the Food and Agriculture Organization of the United Nations and the World Health organization (0.05 mg/kg, 0.1 mg/kg, and 1.5 mg/kg, respectively) in okra, spinach, and cauliflower. The sum of concentrations of the toxic elements (As, Ni, Hg, Cr, Cd, Pb) in vegetables had a range of 0.54-12.08 mg/kg, the highest sum was found in spinach (median 12.08 mg/kg), followed by okra (median 1.68 mg/kg). The EDI was observed for vegetables with a contribution as high as 92% for Cd. Dairy products were found with the highest loading for Ni with a dietary intake of 3.1 mg/kg/day for adults and twice as much for children. Carcinogenic risk for Ni was the highest and found above the threshold for all food categories, as was the case with As. Cumulative carcinogenic and non-carcinogenic risks were mostly contributed by milk and vegetables, in particular, spinach.

New and legacy pesticidal persistent organic pollutants in the agricultural region of the Sultanate of Oman.

Comprehensive air and surface soil monitoring was conducted for new and legacy organochlorine pesticides (OCPs) to fill the knowledge and data gap on the sources and fate of pesticidal persistent organic pollutants (POPs) in the Sultanate of Oman. DDTs in agricultural soil samples ranged from 0.013 to 95.80 ng/g (mean: 8.4 ± 25.06 ng/g), with a median value of 0.07 ng/g. The highest concentration was observed at Shinas, where intensive agricultural practice is prevalent. The dominance of p,p'-DDT in soil and air reflected technical DDT formulation usage in Oman. Among newly enlisted POPs, pentachlorobenzene had the maximum detection frequency in air (47%) and soil (41%). Over 90% of sites reflected extensive past use of hexachlorobenzene. Major OCP isomers and metabolites showed net volatilisation from the agricultural soil, thereby indicating concurrent emission and re-emission processes from the soil of Oman. However, the cleansing effect of oceanic air mass is the possible reason for relatively lower atmospheric OCP levels from a previous study. Although DDT displayed maximum cancer risk, the level is below the permissible limit. DDT primarily stemmed from obsolete stock and inadequate management practices. Hence, we suggest there is a need for DDT regulation in Oman.

A luminous strategy for the recognition of toxic antibiotics in water via efficient energy transfer.

Fluoroquinolones (FQs) are the class of Antibiotics (ABs) that have been extensively used worldwide for the treatment of diseases caused by bacterial infections. In India, most of these untreated ABs and their unused metabolites present in treated and untreated wastewater end up in agricultural land and water bodies. This can accelerate the problem of antimicrobial resistance in the community. Hence, we aim to develop a cost-effective sensor to detect and monitor the presence of such drugs in water bodies. We have prepared a chemically reduced graphene oxide (rGO) integrated luminescent cerium metal-organic framework (MOF) that specifically targets and recognizes ciprofloxacin (CPFX), norfloxacin (NFX), and ofloxacin (OFX) achieving excellent sensing activity. A remarkable quenching of the fluorescence of MOF composite was observed upon interaction with CPFX, NFX, and OFX with 57.9, 46.3, and 51.6 ppb as limits of detection, respectively, through a Forster resonance energy transfer from the Ce-MOF to the analytes. The applicability of the sensor was also examined with real-time samples collected from the rivers of Chennai city and the MOF probe exhibited an appreciable recovery of results. This is the first study on Ce-MOF-based rGO composite providing a solid rationale for fluorescence detection of FQs with exceptional quenching efficiency and very high sensitivity for monitoring FQs in water bodies even in diluted conditions.

Distribution of organochlorine pesticides in surface and deep waters of the Southern Indian Ocean and coastal Antarctic waters.

Antarctica is a remote and pristine region. Yet it plays a vital role in biogeochemical cycles of global anthropogenic contaminants, such as persistent organic pollution (POPs). This work reports the distribution of legacy and new POPs in surface and depth profiles/deeper water of the Southern Indian Ocean (SIO) and the coast of Antarctica (COA). Samples were collected during the 10th Indian Southern Ocean expedition (SOE-10) in the year 2017. Concentrations of ∑HCH (hexachlorocyclohexane), ∑DDT (dichlorodiphenyltrichloroethane), and ∑ENDO (endosulfan) in surface seawater from the SIO region ranged between not detected (ND) to 1.21 pg/Liter (pg L-1) (average. ± s.d.: 0.35 ± 0.42 pg L-1), ND to 1.83 pg L-1 (0.69 ± 84 pg L-1), and ND - to 2.06 pg L-1 (0.56 ± 0., 88 pg L-1), respectively. The concentrations of ∑HCH, ∑DDT, and ∑ENDO in COA ranged from ND to 0.98 pg L-1 (0.25 ± 0.27 pg L-1), ND to 3.61 pg L-1(0.50 ± 1.08 pg L-1), and ND to 2.09 pg L-1 (0.45 ± 0.84 pg L-1), respectively. Concentrations of isomers of endosulfan, and largely of HCHs, suggested an aged source. Some concentration ratios of α-to γ-HCH were close to 1, indicating a contribution from ongoing sources. Results indicate the important role of ocean currents in mediating the transport and detection of OCPs. As such, OCPs dynamics in deeper oceans may play an important role in OCPs cycling in the marine environment.

Sediment-water partitioning and risk assessment of organochlorine pesticides along the urban, peri-urban and rural transects of Krishna River Basin, Peninsular India.

Organochlorine pesticides (OCPs) were widely used in the past for pest control in agricultural lands and vector control programs in India. Due to their persistence and toxic impacts, we have quantified twenty OCPs in surface water, groundwater, and surface sediment samples along the Krishna River Basin (KRB), flowing through Peninsular India. Samples were collected along the urban, peri-urban, and rural transects of the KRB to understand the relation between the occurrence of pesticidal organochlorine pollutants based on the land use and land cover (LULC) and asses potential risk. Diagnostic ratios revealed ongoing Lindane usage in rural and peri-urban transects. On the contrary, the urban transect of the Musi River (MR) showed fresh inputs of technical HCH. The ratios of (p,p'-DDE+ p,p'-DDD)/ΣDDT >0.5 and α/ß-Endosulfan < 2.33 for most of the sites across the three transects for surface water, groundwater, and sediment indicate past DDT and Endosulfan usage across KRB. Excluding p,p'-DDE, and heptachlor in most of the sites, the logKOC' was higher than logKOC for other OCPs in the urban transect. However, for all the OCPs, the logKOC' was lower than logKOC in the peri-urban and rural transects of KRB thereby indicating that riverine sediment is acting as a sink for OCPs. The Krishna River annually transport about 0.24 tons HCH, 0.11 tons of DDT and 0.1 tons of Endosulfan. Despite having low water discharge, the compound-specific fluxes of the Wyra river are higher than the other two tributaries. Ecotoxicological risk assessment based on the Hazard Quotient suggested DDT pose higher risks to scud (zooplankton) and dinoflagellate and diatom (phytoplankton) whereas Endosulfan poses a threat to Bluegill (fish).

Risk assessment of persistent pesticide pollution: Development of an indicator integrating site-specific characteristics.

Detection of high pesticide concentrations in sediments and water often leads to prioritizing a site as being 'at risk'. However, the risk does not depend on pesticide concentration alone, but on other site-specific characteristics also. We developed an indicator that identifies the 'Level of Concern' by integrating five such characteristics: (i) pesticide concentrations in surface and groundwater causing risks to ecological health (ii) impacts on human health, (iii) water scarcity, (iv) agricultural production, and (v) biodiversity richness. We applied this framework in an agricultural region of the Lower Ganges Basin in West Bengal, India. We measured concentrations of selected organochlorine pesticides (OCPs) in surface and groundwater within an 8 km2 area in 2019. Of 20 banned and restricted OCPs, 11 were detected as causing high risk to ecological health and 10 at concentrations above the Accepted Carcinogenic Risk Limit (ACRL) for humans. In the pre-monsoon, the mean concentrations of ΣOCPs in groundwater and surface water were 126.9 ng/L and 104 ng/L, in the monsoon they were 144.7 ng/L and 138 ng/L, and in the post-monsoon 122.1 ng/L and 147 ng/L respectively. In groundwater, no significant seasonal difference was observed in most pesticides. In the surface water, 7 pesticides were significantly higher in the monsoon and post-monsoon, which may be attributed to increased runoff as well as post monsoon application of OCPs. In September 2022 we again measured OCP concentrations in surface water and sediment. The mean concentration of 14 of the 20 measured OCPs were found to be significantly lower in the post-pandemic period compared to the pre-pandemic time. These lower pesticide concentrations may indicate a reduced use of OCPs in agricultural practices during the pandemic. This area was identified as being at the highest Level of Concern, even though the OCP concentrations alone conformed to general guidelines.

Unlocking India's Potential in Managing Endocrine-Disrupting Chemicals (EDCs): Importance, Challenges, and Opportunities.

Endocrine-disrupting chemicals (EDCs) are a prime concern for the environment and health globally. Research shows that in developing countries such as India both the environment and human populations are severely exposed to EDCs and consequently experience rising incidents of adverse health effects such as diabetes and cancers. In this paper, we discuss the current EDC management approach in India, critically assess its limitations, and describe opportunities for potential improvements. Foremost, current EDC management actions and interventions in India are fragmented and outdated, and far behind the modern and comprehensive approaches adopted in the European Union and other developed countries. Strong and well-planned actions are required on various fronts of science, policy, commerce, and public engagement. These actions include the adoption of a dedicated and modern regulatory framework for managing EDCs, enhancing capacity and infrastructure for EDC monitoring in the environment and human population, employing public-private partnership programs for not only managing EDCs but also in the sectors that indirectly contribute toward the mismanagement of EDCs in the country, and raising awareness on EDCs and promoting health-preserving consumption habits among the public. As India hosts a large proportion of the global human population and biodiversity, the success or failure of its actions will substantially affect the direction of global efforts to manage EDCs and set an example for other developing countries.

Antibiotics in sewage treatment plants, receiving water bodies and groundwater of Chennai city and the suburb, South India: Occurrence, removal efficiencies, and risk assessment.

The presence of antibiotics in the aqueous environment can alter the water microbiome, inducing antimicrobial resistance genes. Hence, the occurrence of 18 antibiotics belonging to sulfonamides, fluoroquinolones, tetracyclines, phenicols, and macrolides classes were investigated in surface water, groundwater, and sewage treatment plants in Chennai city and the suburbs. Fluoroquinolones had the maximum detection frequency in both influent and effluent samples of urban and suburban STPs, with ofloxacin and ciprofloxacin showing the highest influent concentrations. Erythromycin was the predominant antibiotic in surface water samples with an average concentration of 194.4 ng/L. All the detected antibiotic concentrations were higher in the Buckingham Canal compared to those in Adyar and Cooum rivers, possibly due to direct sewer outfalls in the canal. In groundwater samples, ciprofloxacin showed the highest levels with an average of 20.48 ng/L and the concentrations were comparable to those of surface water. The average sulfamethazine concentration in groundwater (5.2 ng/L) was found to be slightly higher than that of the surface water and much higher than the STP influent concentrations. High levels of ciprofloxacin and sulfamethazine in groundwater may be because of their high solubility and wide use. Moreover, erythromycin was completely removed after treatment in urban STPs; FQs showed relatively lesser removal efficiency (2.4-54%) in urban STPs and (8-44%) in suburban STP. Tetracyclines and phenicols were not detected in any of the samples. Ciprofloxacin and azithromycin in surface water pose a high risk in terms of estimated antibiotic resistance. This study revealed that the measured surface water concentration of antibiotics were 500 times higher for some compounds than the predicted calculated concentrations from STP effluents. Therefore, we suspect the direct sewage outlets or open drains might play an important role in contaminating surface water bodies in Chennai city.

Legacy and new chlorinated persistent organic pollutants in the rivers of south India: Occurrences, sources, variations before and after the outbreak of the COVID-19 pandemic.

During pre-pandemic time, organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were investigated in the surface water of Periyar River (PR) and Bharathappuzha River (BR) in Ernakulam and Malappuram districts of Kerala, respectively and Adyar River (AR) and Cooum River (CR) in Chennai district of Tamil Nadu. After the outbreak of COVID-19 pandemic, variation in OCPs and PCBs were evaluated for AR and CR. Dominance of ß-HCH and γ-HCH in south Indian rivers indicate historical use of technical HCH and ongoing use of Lindane, respectively. In > 90 % sites, p,p'-DDT/ p,p'-DDE ratio was < 1, indicating past DDT usage. However during the outbreak of the COVID-19 pandemic, elevated p,p'-DDT in AR and CR reflects localized use of DDT possibly for vector control. Similarly, during the first wave of pandemic, over a 100-fold increase in PCB-52 in these rivers of Chennai mostly via surface run-off and atmospheric deposition can be reasoned with open burning of dumped waste including added waste plastic in the solid waste stream. On contrary, a significant (p < 0.05) decline of dioxin-like PCBs level, suggests lesser combustion related activities by the formal and informal industrial sectors after the lockdown phase in Tamil Nadu. Eco-toxicological risk assessment indicated a higher risk for edible fish in PR due to endosulfan.

Migration of Plasticizers from Polyethylene Terephthalate and Low-Density Polyethylene Casing into Bottled Water: A Case Study From India.

Mineral bottled water packed in three polymers viz., virgin polyethylene terephthalate (PET), recycled PET, and low-density polyethylene (LDPE) were investigated for the occurrence, migration, and health risk of phthalic acid esters (PAEs) at 25 °C, 35 °C, and 45 °C. The average concentration of six USEPA priority PAEs in refrigerated water samples was highest in recycled PET> LDPE > virgin PET. The highest leaching was seen at 45 °C after 2 days for LDPE water packets with ∑6PAEs amounting to 64,300 ng/L. Similarly, for recycled PET, the highest migration was seen at 45 °C after seven days (3,800 µg/L). Bis 2-ethyl hexyl phthalate (DEHP) and di-n-butyl phthalate (DnBP) were the predominant plasticizers from PET bottles and LDPE water packets, respectively. Predicted concentration after three weeks based on best fit obtained through the polynomial model for PET bottles was seen higher than the recommended limit suggested by USEPA (6 µg/L) and WHO (8 µg/L).

Interlinkage Between Persistent Organic Pollutants and Plastic in the Waste Management System of India: An Overview.

Improper handling of plastic waste and related chemical pollution has garnered much attention in recent years owing to the associated detrimental impacts on human health and the environment. This article reports an overview of the main interlinkages between persistent organic pollutants (POPs) and plastic in the waste management system of India. Both plastics and POPs share certain common traits such as persistence, resistance to biological degradation, and the ability to get transported over long distances. Throughout the processes of production, consumption, and disposal, plastics interact with and accumulate POPs through several mechanisms and end up co-existing in the environment. Plastic waste can undergo long-range transport through rivers and the oceans, break down into microplastics and get transported through the air, or remain locked in waste dump yards and landfills. Over time, environmental processes lead to the leaching and release of accumulated POPs from these plastic wastes. Plastic recycling in the Indian informal sector including smelting, scrubbing, and shredding of plastic waste, is also a potential major POPs source that demands further investigation. The presence of POPs in plastic waste and their fate in the plastic recycling process have not yet been elucidated. By enhancing our understanding of these processes, this paper may aid policy decisions to combat the release of POPs from different waste types and processes in India.

Chemical remediation and advanced oxidation process of polychlorinated biphenyls in contaminated soils: a review.

Polychlorinated biphenyls (PCBs) are synthetic organic compounds ubiquitously distributed worldwide due to their persistence, long-range atmospheric transport, and bioaccumulation. Owing to teratogenic properties, PCBs are a global environmental problem. Different physical, biological, and chemical techniques are utilized for the remediation of PCBs. This review paper discusses the recent development in photocatalytic and chemical techniques for the remediation of PCBs in contaminated soils. In particular, the photocatalytic degradation of PCBs combined with soil washing, Fe-based reductive dichlorination, and advanced oxidation process (Fenton advance oxidation and persulfate oxidation) is discussed and reviewed in detail. The review suggested that advanced oxidation is an efficient remediation technique with 77-99% of removal efficiency of PCBs. Persulfate oxidation is the most suitable technique which could work at normal environmental conditions (such as pH, temperature, soil organic matter (SOM), etc.). Different environmental factors such as pH, temperature, and SOM affect the Fe-based reductive dechlorination and Fenton advance oxidation techniques. The surfactants and organic solvents used in soil washing combined with photocatalytic degradation affect the degradation capability of these techniques. This review will contribute to PCBs degradation by the detailed discussion of development in chemical technique future perspective and research needs.

Endocrine-disrupting chemicals used as common plastic additives: Levels, profiles, and human dietary exposure from the Indian food basket.

Endocrine-disrupting chemicals (EDCs) such as phthalic acid esters (PAEs) and bisphenol A (BPA) are the most widely used plastic additives in polymeric materials. These EDCs are ubiquitously distributed in the environment. Hence selected PAEs and BPA were investigated in twenty-five food types and drinking water (supply and packaged) from the metropolitan city, Delhi, and the peri-urban areas of a non-metropolitan city, Dehradun. Except cabbage and orange, the sum of thirteen PAEs (∑13PAEs) and BPA in all the other food types were significantly higher in Delhi over Dehradun (p < 0.01). Highest mean ∑13PAEs (665 ng/g) and BPA (73 ng/g) were observed in cottage cheese and potatoes, respectively followed by fish (PAEs - 477 ng/g, BPA - 16 ng/g). Supply water from the west zone of Delhi was found to contain the highest concentration of BPA (309 ng/L) and ∑13PAEs (5765 ng/L) with the dominance of diethyl phthalate (DEP). Based on the compositional profile and compound-wise principal component analysis, environmental contamination and food processing were attributed as significant sources of most priority PAEs in food samples. Di-ethyl hexyl phthalate (DEHP) was over 100-fold higher in the bottled water from local brands than composite bottled water samples. Packaging material was identified as a source for di-n-butyl phthalate (DnBP) in packaged food. This study observed the highest estimated daily dietary intake (EDI) in the high-fat-containing food products viz., cottage cheese, and fish from north Delhi. High bioaccumulation of BPA can be a possible reason for elevated EDI in vegetables and local fish of Delhi. Unlike Dehradun, EDI for ∑13PAEs and BPA was slightly higher for the non-vegetarian adult when compared to the vegetarian adult. DEHP and DnBP exhibited the highest estimated estrogenic potential for bottled water from local brands. Dietary exposure due to six priority PAEs contamination in food stuffs was two to four-fold higher in Delhi than Dehradun for adult man and woman.